SCALMS catalysis
Overview
Dissolving small amounts of catalytically active metal in a matrix metal (like Ga or In) results in alloys that become liquid under elevated reaction conditions. These supported catalytically active liquid metal solutions (SCALMS) represent a new class of heterogeneous catalysts, since they enable single-atom catalysis at dynamic gas-alloy interfaces. The high dynamics at this interface and the electronic properties of the surrounding matrix metal induce completely new activity and selectivity patterns in single atom catalysis (SAC). Moreover, such systems can be more stable compared to traditional heterogeneous counterparts, since coking is less likely to occur on highly dynamic surfaces.
Selected publications
- Raman N., Maisel S., Grabau M., Taccardi N., Debuschewitz J., Wolf M., Wittkämper H., Bauer T., Wu M., Haumann M., Papp C., Görling A., Spiecker E., Libuda J., Steinrück HP., Wasserscheid P.:
Highly Effective Propane Dehydrogenation Using Ga-Rh Supported Catalytically Active Liquid Metal Solutions
In: ACS Catalysis (2019), S. 9499-9507
ISSN: 2155-5435
DOI: 10.1021/acscatal.9b02459
- Wolf M., Raman N., Taccardi N., Haumann M., Wasserscheid P.:
Coke Formation during Propane Dehydrogenation over Ga−Rh Supported Catalytically Active Liquid Metal Solutions
In: ChemCatChem (2020)
ISSN: 1867-3880
DOI: 10.1002/cctc.201901922
- Oshin O., Nair SS., Taccardi N., Wolf M., Soegaard A., Haumann M., Wasserscheid P.:
Stable and Selective Dehydrogenation of Methylcyclohexane using Supported Catalytically Active Liquid Metal Solutions – Ga52Pt/SiO2 SCALMS
In: ChemCatChem (2020)
ISSN: 1867-3899
DOI: 10.1002/cctc.202000671
- Wolf M., Raman N., Taccardi N., Horn R., Haumann M., Wasserscheid P.:
Capturing spatially resolved kinetic data and coking of Ga-Pt Supported Catalytically Active Liquid Metal Solutions during propane dehydrogenation in situ
In: Faraday Discussions (2020)
ISSN: 1359-6640
DOI: 10.1039/D0FD00010H
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